Bimolecular recombination in polymer/fullerene bulk heterojunction solar cells

Charge Carrier Recombination in Bulk Heterojunction Organic Solar Cells

Photovoltaic phenomenon was first observed by E. Becquerel (Becquerel) in 1839. He observed the electric current-lit silver electrode, immersed in the electrolyte. In 1894, taking advantage of the observed photoconductivity phenomenon in amorphous selenium the semiconductor solar cell was developed. The very first silicon p-n junction solar cell was made in 1954, energy conversion efficiency of...

The Importance of Fullerene Percolation in the Mixed Regions of PolymerFullerene Bulk Heterojunction Solar Cells

wileyonlinelibrary.com © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim J. A. Bartelt, Z. M. Beiley, W. R. Mateker, Dr. K. R. Graham, Prof. M. D. McGehee Department of Materials Science and Engineering Stanford University Stanford, CA 94305, USA E-mail: [email protected] Dr. E. T. Hoke Department of Applied Physics Stanford University Stanford, CA 94305, USA J. D. Douglas, Prof. J. M. J. F...

Bulk Heterojunction Solar Cells — Opportunities and Challenges

Molecular weight dependent bimolecular recombination in organic solar cells.

Charge carrier recombination is studied in operational organic solar cells made from the polymer:fullerene system PCDTBT:PC71BM (poly[N-9''-heptadecanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)]: [6,6]-phenyl-C70-butyric acid methyl ester). A newly developed technique High Intensity Resistance dependent PhotoVoltage is presented for reliably quantifying the bimolecul...

Hydrogen bonding in bulk heterojunction solar cells: A case study

Small molecules with dithieno[3,2-b;2',3'-d]thiophene as central building block and octyl cyanoacetate and octyl cyanoacetamide as different terminal building blocks have been designed and synthesized. The amide containing small molecule can form intermolecular hydrogen bonding between N-H...O = C of the amide group. The photovoltaic properties and active layer morphologies of the two molecules...